Self-assembly of catalytically active colloidal molecules: Tailoring activity through surface chemistry
Physical Review Letters 112:6 (2014)
Abstract:
A heterogeneous and dilute suspension of catalytically active colloids is studied as a nonequilibrium analogue of ionic systems, which has the remarkable feature of action-reaction symmetry breaking. Symmetrically coated colloids are found to join up to form self-assembled molecules that could be inert or have spontaneous activity in the form of net translational velocity and spin depending on their symmetry properties and their constituents. The type of activity can be adjusted by changing the surface chemistry and ambient variables that control the surface reactions and the phoretic drift. © 2014 American Physical Society.Run-and-tumble dynamics in a crowded environment: Persistent exclusion process for swimmers
Physical Review E - Statistical, Nonlinear, and Soft Matter Physics 89:1 (2014)
Abstract:
The effect of crowding on the run-and-tumble dynamics of swimmers such as bacteria is studied using a discrete lattice model of mutually excluding particles that move with constant velocity along a direction that is randomized at a rate α. In stationary state, the system is found to break into dense clusters in which particles are trapped or stopped from moving. The characteristic size of these clusters predominantly scales as α-0.5 in both one and two dimensions. For a range of densities, due to cooperative effects, the stopping time scales as T1d0.85 and as T2d0.8, where Td is the diffusive time associated with the motion of cluster boundaries. Our findings might be helpful in understanding the early stages of biofilm formation. © 2014 American Physical Society.Instabilities and topological defects in active nematics
EPL 105:1 (2014)
Abstract:
We study a continuum model of an extensile active nematic to show that mesoscale turbulence develops in two stages: i) ordered regions undergo an intrinsic hydrodynamic instability generating walls, lines of strong bend deformations; ii) the walls relax by forming oppositely charged pairs of defects. Both creation and annihilation of defect pairs reinstate nematic regions which undergo further instabilities, leading to a dynamic steady state. We compare this with the development of active turbulence in a contractile active nematic. © Copyright EPLA, 2013.Enzyme-driven chemotactic synthetic vesicles
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY 248 (2014)
Noy and Golestanian reply
Physical Review Letters 111:17 (2013)